2,4,6-Tris(1-oxo-2-pyridylsulfanylmethyl)mesitylene methanol solvate
نویسندگان
چکیده
In the title compound, C(27)H(27)N(3)O(3)S(3)·CH(4)O, the dihedral angles formed by the mesitylene ring with the three oxopyridyl rings are 89.6 (1), 75.5 (1) and 80.69 (1)°, indicating that all three are nearly perpendicular to the mesitylene ring. Intra-molecular C-H⋯S hydrogen bonds generate S(6) ring motifs. The crystal structure is stabilized by intra-molecular C-H⋯S and inter-molecular C-H⋯O hydrogen bonds and weak C-H⋯π inter-actions.
منابع مشابه
4,4′,4′′-Tris(2-pyridyl)-2,2′,2′′-[(2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene)tris(sulfanediyl)]tripyrimidine
The title compound, C(39)H(33)N(9)S(3), features a mesitylene unit substituted with three thio-ether arms. The distances from the center of mesitylene unit to the N atoms of the three pyridine rings in the arms are 10.05 (1), 9.94 (3) and 8.79 (3) Å. The crystal structure shows weak intra-molecular C-H⋯N hydrogen bonds.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008